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A carbamoyl chloride is the functional group with the formula R2NC(O)Cl. The parent carbamoyl chloride, H2NCOCl is unstable, but many N-substituted analogues are known. Most examples are moisture sensitive, colourless, and soluble in nonpolar organic solvents. An example is dimethylcarbamoyl chloride (m.p. −90 °C and b.p. 93 °C). Carbamoyl chlorides are used to prepare a number of pesticides, e.g. carbofuran and aldicarb.〔 Peter Jäger, Costin N. Rentzea and Heinz Kieczka "Carbamates and Carbamoyl Chlorides" in Ullmann's Encyclopedia of Industrial Chemistry, 2012, Wiley-VCH, Weinheim. 〕 ==Production and examples== Carbamoyl chlorides are prepared by the reaction of an amine with phosgene: :2 R2NH + COCl2 → R2NCOCl + ()Cl They also arise by the addition of hydrogen chloride to isocyanates: :RNCO + HCl → RNHCOCl In this way, carbamonyl chlorides can be prepared with N-H functionality. 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Carbamoyl chloride」の詳細全文を読む スポンサード リンク
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